Estimating sulfide capacities for ternary systems with limited solubility
2012
In view of successful application of mass triangle model in thermophysical
properties, in the current work, the mass triangle model was extended to
evaluate sulfide capacities of ternary systems with limited homogeneous
region. Four ternary systems of Al2O3-FeO-SiO2, FeO-CaO-SiO2, CaO-CaCl2-CaF2
and CaO-CaF2-SiO2 were chosen to calculate iso-sulfide capacity based on the
limited boundary data. The good agreement between reference data and
calculated data indicated that this model is feasible and will play an
indispensable role in the future. Compared with optical basicity model, the
results obtained by mass triangle model are still competitive when containing
Cl- and F- in the molten slag due to lacking the optical basicity values.
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