A spectroscopic investigation of incompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol): Hydrogen-bonded interaction and host–guest complex

Abstract 1 H NMR dilution experiment and FTIR were used to investigate the hydrogen bonded interaction in three different types of incompletely condensed silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol). For POSS-triol, there existed a dynamic equilibrium between single molecule and hydrogen-bonded dimer, and the dimerization constants ( K dim ) of POSS-triol in different solvents were determined by 1 H NMR dilution experiment. In addition, based on hydroxy group which acted as hydrogen bond donors, the possibility of three POSS silanols as anion receptors to form host–guest complexes was also explored in this paper.