A measurement method for isotope fractionation of 35Cl and 37Cl by a conventional through-diffusion experiment

Abstract Chlorine is geochemically stable and is widely used as a groundwater tracer. Stable isotopes of chlorine ( 35 Cl and 37 Cl) are fractionated by diffusion and are used to characterize diffusion-dominant systems, understand seawater intrusion and identify the origin of chlorine. However, a method for measuring the fractionation factor by diffusion (α = D Cl−35  / D Cl−37 ) has not been established for rock samples. We propose a method for measuring α using a conventional through-diffusion experiment, in which a sample is embanked by a high- to low-concentration tank. This study shows that theoretically, the diffusive flux in a through-diffusion experiment should have mass ratio fractionated by diffusion and that the difference between δ 37 Cl in the high- to low-concentration tank will approach to 10 3 ln α with time. The results of the through-diffusion experiment showed a significant difference between δ 37 Cl in the high- and low-concentration tanks. Measured α ranged from 1.0015–1.0022, which is in good agreement with previous studies. Moreover, the sampling period and correction method are suggested to determine α excluding errors due to an unsteady state. The proposed method is applicable to other isotopes to measure α and will contribute to a more quantitative evaluation of Cl and δ 37 Cl profiles.