Effects of SO42− ions on the corrosion of GH3535 weld joint in FLiNaK molten salt

Abstract The present work studied the impact of SO 4 2− ions on the corrosion behaviors of GH3535 weld joint in FLiNaK molten salt. The concentration of SO 4 2− ions in the FLiNaK molten salt was controlled by adjusting the quantity of Na 2 SO 4 added into the salt. Results indicate that the SO 4 2− ions in the FLiNaK salt speed up the corrosion rate remarkably by promoting the dissolution of Cr from the alloy matrix into the salt. With the concentration of SO 4 2− ions in the FLiNaK salt increases from 100 ppm to 1000 ppm, the weight losses and the Cr depletion layer depths of the corroded specimens increase linearly. Even in the case of the heavy corrosion attack caused by the SO 4 2− ions, the corrosion performance is similar between the base zone and fusion zone in the GH3535 weld joint. It is demonstrated that the structural diversity caused by the welding process has little impact on the corrosion performances of GH3535 alloy in FLiNaK molten salt.