Changes in organic acids, polyphenolic and elemental composition of rosé sparkling wines treated with mannoproteins during over-lees aging

Abstract The effect of mannoproteins on the evolution of rose sparkling wines during over-lees aging was investigated on the basis of the chemical characterization of polyphenols, organic acids, macro- and microelements using a combined analytical approach. Variations on these constituents were assessed using Raman and near-infrared spectroscopy. During the biological aging, caffeic acid, catechin, gallic acid and malvidin-3- O -glucoside were the most abundant polyphenolics in the rose wines. The phenolic compound tyrosol, a fermentation derivative, was found at concentrations up to 98.07 mg L −1 . The addition of mannoproteins significantly affected the concentrations of organic acids and individual polyphenolic compounds, particularly trans- resveratrol, quercetin, catechin, p -coumaric and hydroxybenzoic acids that showed increased concentrations over time. The positive effects of mannoproteins were mainly observed at the end of the biological aging. The mineral composition remained stable, while potassium was the most abundant mineral in all wines. The observed changes involving these constituents may offer new insights on their behavior during wine aging and on the bioactive and nutritional quality of rose sparkling wines.