The 21 μm and 30 μm emission features in carbon-rich objects

We review the observational properties and possible carriers of the 21 and 30 μm features seen in the spectra of evolved carbon-rich objects. The 30 μm feature is generally taken to be due to MgS, possibly in combination with other sulfides. It is commonly assumed that the sulfides coat grains of SiC or amorphous carbon, but it remains unclear if coated grains can produce the observed feature given the low relative abundance of sulfur and the optical constraints on the thickness of the coating and size of the grains. The lack of optical constants for MgS at wavelengths below 1 μm hampers attempts to model the dust shells of these objects. A small number of alternative carriers have been proposed, but these have not been investigated thoroughly. The situation for the 21 μm feature is more ambiguous. Many carriers have been proposed, but each has issues, and none have gained broad support. The feature only appears in carbon-rich objects which have evolved off of the asymptotic giant branch but have not yet become planetary nebulae. The spectral class of the central star is typically F or G. The transient nature of the 21 μm feature is an important clue to the nature of its carrier. It appears with a variety of other infrared emission features related to complex hydrocarbons, including aliphatic species and polycyclic aromatic hydrocarbons, but correlations with specific features have proven difficult to quantify.