Diastereoselective Synthesis of 3,4-Benzomorphan Derivatives via Tandem [5 + 1]/Hemiaminalization of (2-Aminoaryl)divinyl Ketones.

Yifei Li,Chengjie Feng,Hui Shi,Xianxiu Xu

Diastereoselective Synthesis of 3,4-Benzomorphan Derivatives via Tandem [5 + 1]/Hemiaminalization of (2-Aminoaryl)divinyl Ketones.

2016

Yifei Li
Chengjie Feng
Hui Shi
Xianxiu Xu

The single step metal-free title reaction between (2-aminoaryl)divinyl ketones and nitromethane as well as other nucleophilic active methylene compounds tolerates various functional groups.

Keywords:

Nucleophile
Methylene
Benzomorphan derivatives
Nitromethane
Tandem
Organic chemistry
Chemistry
single step

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