SuFEx Activation with Ca(NTf2)2: A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides.

Subham Mahapatra,Cristian P. Woroch,Todd William Butler,Sabrina N. Carneiro,Sabrina C. Kwan,Samuel R. Khasnavis,Junha Gu,Jason K. Dutra,Beth C. Vetelino,Justin Bellenger,Christopher W. am Ende,Nicholas D. Ball

SuFEx Activation with Ca(NTf2)2: A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides.

2020

Subham Mahapatra
Cristian P. Woroch
Todd William Butler
Sabrina N. Carneiro
Sabrina C. Kwan
Samuel R. Khasnavis
Junha Gu
Jason K. Dutra
Beth C. Vetelino
Justin Bellenger
Christopher W. am Ende
Nicholas D. Ball

A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a diverse set of s...

Keywords:

Chemistry
DABCO
Organic chemistry
Calcium
Sulfonyl

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