Asymmetric synthesis of α-amino acids by reduction of N-tert-butanesulfinyl ketimine esters.
2011
A highly regio- and diastereoselective reduction of various N-tert-butanesulfinyl ketimine esters with l-Selectride resulting in the formation of α-amino acids is reported. This method is quite general and also practical for the preparation of both enantiomers of aryl or aliphatic α-amino acids in high yields.
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