Corrections to charge exchange spectroscopic measurements in TFTR due to energy-dependent excitation rates

The use of charge exchange spectroscopy to determine plasma rotation speeds and ion temperature is complicated by the energy dependence of the excitation cross sections. The Doppler‐broadened spectral line shape is distorted by the relative velocity between the neutral hydrogen atoms of the injected beam and impurity ions. The asymmetric nature of the energy dependence of this cross section causes a nonmotional shift of the line center and a nonthermal change in the linewidth. These effects vary with the angles between the beam direction, rotation velocity direction, and direction of the viewing sightline. When viewing two neutral beams at different angles on TFTR, the two measurements of vφ(r) show discrepancies of about 20%–30% with each other. The calculation of the spectral intensity profiles using the available excitation rates overcorrects these discrepancies and indicates the need for better excitation coefficients.