Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.

Rong-Jia Wei,Ryohei Nakahara,Jamie M. Cameron,Graham N. Newton,Takuya Shiga,Hajime Sagayama,Reiji Kumai,Youichi Murakami,Hiroki Oshio

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.

2016

Rong-Jia Wei
Ryohei Nakahara
Jamie M. Cameron
Graham N. Newton
Takuya Shiga
Hajime Sagayama
Reiji Kumai
Youichi Murakami
Hiroki Oshio

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Keywords:

Photochemistry
Trigonal pyramidal molecular geometry
Square pyramidal molecular geometry
Inorganic chemistry
Trigonal bipyramidal molecular geometry
Cyanide
Spin transition
Chemistry
T-shaped molecular geometry
Intramolecular force
Electron transfer
Crystallography

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