Salt deposition and brine evolution in the Granada Basin (Late Tortonian, SE Spain)

2013 
Abstract A group of sedimentary basins in the Betic Chain were formed during the Middle-Late Miocene as a result of the closure of the Tethys during the Alpine orogeny. In the Late Miocene (Tortonian–Messinian) the connections between the Atlantic Ocean and Mediterranean Sea were interrupted and those basins hosted major evaporites. The Granada Basin, an ‘inner basin’ located far from the Mediterranean, contains a thick rock salt deposited during the latest Tortonian in the transition from marine to non-marine conditions. In the centre of the basin, three halite-bearing units overlie a basal anhydrite bed: the Lower Halite Unit, the Intermediate Sandstone Unit and the Upper Halite Unit. Fluid inclusion compositions and bromine concentrations in halite, together with stable isotopes (δ 34 S sulfate , δ 18 O sulfate and 87 Sr/ 86 Sr) indicate a mixture of different inflow waters in the Granada Basin, beginning with a marine lagoon that evolved into a salt-pan strongly isolated from the sea. Saline waters evolved from sulfate-rich marine-derived to sulfate-depleted non-marine brines influenced by the addition of CaCl 2 -rich inputs. These CaCl 2 -rich waters were probably linked to thermal fluids associated with a major crustal fracture system (Crevillente or Cadiz-Alicante fault system) that cuts through the Granada Basin.
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