Asymmetric Addition of Arylboronic Acids to Glyoxylate Catalyzed by a Ruthenium/Me‐BIPAM Complex.

Yasunori Yamamoto,Tomohiko Shirai,Norio Miyaura

Asymmetric Addition of Arylboronic Acids to Glyoxylate Catalyzed by a Ruthenium/Me‐BIPAM Complex.

2012

Yasunori Yamamoto
Tomohiko Shirai
Norio Miyaura

The enantioselective synthesis of α-hydroxy esters (III) by Ru-catalyzed 1,2-addition of arylboronic acids (II) to tert-butyl glyoxylates (I) is described.

Keywords:

Glyoxylates
Enantioselective synthesis
Glyoxylate cycle
Ruthenium
Catalysis
Chemistry
Organic chemistry

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