Enhanced long-term cyclability in Li-Rich layered oxides by electrochemically constructing a LixTM3-xO4-type spinel shell
2020
Abstract The poor long-term cycling stability, including the fast capacity fade and the severe voltage decay, has become the main concern hindering the practical application of Li-rich layered oxides, a promising cathode for high-energy-density Li-ion battery. Herein, we design and electrochemically construct a ∼10 nm-thick LixTM3-xO4-type (TM = Ni, Co, Mn, 0 4.5 V) and Mn dissolution, thereby suppressing the structural degradation from the layered phase to the spinel phase in the bulk, eventually significantly enhancing the long-term cycling stability. This study adds richness into the Mn-based spinel phase system and provides a new heterostructure design strategy to improve the electrochemical performance of Li-rich layered cathodes and beyond.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
62
References
11
Citations
NaN
KQI