(001) Facet Dominated Hierarchically Hollow Na2Ti3O7 as a High-Rate Anode Materials for Sodium-Ion Capacitors

2019 
Sodium-ion capacitors (SICs) have shown great potential to combine the merits of high-power capability of traditional capacitor and high energy capability of the battery. However, the sluggish kinetics and inferior stability of conventional sodium-ion storage anode materials are major challenges for the practical utilization of SICs. In this work, interconnected urchin-like hollow Na2Ti3O7 (Na2Ti3O7-IcUH) chains were designed and prepared by a simple one step template-assisting method. Through a variety of controlled experiments, we explored how to effectively engineer the crystal-oriented growth and string the urchin-like spheres together. Benefiting from its urchin-like hollow structure and fully exposed (001) facet, the resulting Na2Ti3O7-IcUH exhibits a superior rate capability of 96.2 mAh g-1 at 5 A g-1. Meanwhile, the interconnected three-dimensional (3D) primary structure endows Na2Ti3O7-IcUH with excellent cyclic stability (15% capacity loss at 5 A g-1 after 2000 cycles). By coupling with an activ...
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