Engineering Metallic MoS2 Monolayers with Responsive Hydrogen Evolution Electrocatalytic Activities for Enzymatic Reaction Monitoring
2021
The use of a Schlenk line (SL) promotes a strategy involving N-butyllithium for the chemical exfoliation of layered crystals, with the remarkable merits of being low risk and allowing “one-pot” operation. Significantly, metallic-phase and defect-abundant nanosheets are synthesized from SL-exfoliated molybdenum disulphide (SL-MoS2), exhibiting the desired morphological features with a high percentage of monolayers and uniform planar size. Additionally, SL-MoS2 has the excellent structural features of a metallic phase and abundant defects, thereby supporting high activity during the electrocatalytic hydrogen evolution reaction (HER). Nevertheless, the unique structural and morphological characteristics of SL-MoS2 are proved to cause the rapid dissociation of the SL-MoS2 nanosheets in H2O2-rich environments, and the electrocatalytic performance accordingly declines. The HER current density, which is dependent on the number of active sites of SL-MoS2, specifically reflects the reactive-oxygen-species-based degradation of the SL-MoS2 nanoprobes; this can contribute to the electrochemical monitoring of enzyme-associated biological targets and processes using developed chips based on SL-MoS2-modified carbon fibers.
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