Shipboard Characterization of Tuvalu, Samoa, and Lau Dredge Samples Using Laser-Induced Breakdown Spectroscopy (LIBS):

Chemical analysis using laser-induced breakdown spectroscopy (LIBS) is well suited for field applications and was applied here for shipboard characterization of a large sample set during the RR1310 rock dredging expedition to the Tuvalu Seamounts. Although recently the most common data treatment for LIBS has consisted of a partial least squares approach to define sample groupings, we show that quantitative data of useful quality can be obtained with a univariate approach. Here, our analysis goal was a quantitative comparison of the total alkali (Na2O + K2O) versus silica (SiO2) contents of 586 representative dredge samples with known ranges in common rock types. Out of those samples, >400 form a single large group of alkalic basalts with minor basanites/tephrites (SiO2: 43–48 wt%, Na2O + K2O: 3–5 wt%), similar to known shield-stage compositions of the Rurutu and Samoa hotspots in the sampling area. In contrast, several dredge hauls contain samples with compositions that do not overlap with the majority of...