Structural and magnetic properties of a novel ternary intermetallic compound CePd3Sn2

Abstract We synthesized a new ternary stannide CePd 3 Sn 2 and determined its crystal structure from single crystal x-ray diffraction. This compound crystallizes in the orthorhombic structure with space group Pnma (No.62). One-dimensional chains of the shortest Ce-Ce contacts at 0.47663(1) nm run along the b axis. Both specific heat C and susceptibility χ of polycrystalline samples show a pronounced peak at T N  = 0.6 K indicating an antiferromagnetic order. An obvious tail in C ( T ) appears in the temperature range from T N up to 3 K where the magnetic entropy S m reaches Rln2. Meanwhile, the electrical resistivity ρ exhibits an upward curvature without showing any sign of Kondo scattering. The unusual behaviors of C ( T ) and ρ ( T ) above T N are attributed to antiferromagnetic short-range correlations in the Ce-Ce chain.