Dielectric and ac ionic conductivity investigation of Li 2 SrP 2 O 7

The pyrophosphate Li2SrP2O7 compound has been synthesized by the classic ceramic method and characterized by X-ray diffraction, IR, Raman and electrical impedance spectroscopy. Detailed electrical properties of the compound were analyzed as a function of frequency (209 Hz–1 MHz) and temperature (519–628) K. Impedance analysis exhibits the grain and grain boundary contribution to the electrical response of the sample. The temperature dependence of these contribution obey the Arrhenius law with activation energies (1.03 ± 0.05) and (1.25 ± 0.05) eV, respectively. The ac conductivity for grain contribution was interpreted using the universal Jonscher’s power law. The temperature dependence of frequency exponent s was investigated to understand the conduction mechanism. The correlated barrier hopping model was found to be the best model describing the conduction mechanism.