Self‐Assembly of Aggregation‐Induced‐Emission Molecules

: The last decade has witnessed rapid developments in aggregation-induced emission (AIE). In contrast to traditional aggregation, which causes luminescence quenching (ACQ), AIE is a reverse phenomenon that allows robust luminescence to be retained in aggregated and solid states. This makes it possible to fabricate various highly efficient luminescent materials, which opens new paradigms in a number of fields, such as imaging, sensing, medical therapy, light harvesting, light-emitting devices, and organic electronic devices. Of the various important features of AIE molecules, their self-assembly behavior is very attractive because the formation of a well-defined emissive nanostructure may lead to advanced applications in diverse fields. However, due to the nonplanar topology of AIEgens, it is not easy for them to self-assemble into well-defined structures. To date, some strategies have been proposed to achieve the self-assembly of AIEgens. Herein, we summarize the most recent approaches for the self-assembly of AIE molecules. These approaches can be sorted into two classes: 1) covalent molecular design and 2) noncovalent supramolecular interactions. We hope this will inspire more excellent work in the field of AIE.