Stereoselective Preparation of Highly Functionalized (Z)-3-Copper Enoates by an Iodine-Copper Exchange Reaction
2006
3-Iodoenoates are readily converted into the corresponding alkenylcopper species with complete retention of configuration of the double bond via an iodine-copper exchange reaction. Quenching reactions with various electrophiles provide highly functionalized enoates in good yields.
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