Yttrium germole dianion complexes with Y–Ge bonds

The reactions of dipotassium 3,4-dimethyl-2,5-bis(trimethylsilyl)-germole dianion K2[1] with YCl3 and Cp*YCl2 (Cp* = cyclopentadienyl) in THF at room temperature afforded the dianion salt [(K-cryptand-222)2][1-YCl3] (K2[2]) and the dimeric complex [1-Y-Cp*]2 (3), respectively. While the polymeric complex {[(1)2-Y-K(toluene)]2}n (4) was obtained from the reaction of K2[1] and half molar equivalent of YCl3(THF)3.5 in toluene at 80 °C. The germole dianions in complexes 3 and 4 feature η5/η1 coordination interactions with the yttrium atoms. They represent the first examples of rare earth (RE) complexes containing RE–Ge bonds other than the RE–GeR3 structural type.