Enhanced Electrochemical Performance of Ni-Rich Cathode Materials with Li₁.₃Al₀.₃Ti₁.₇(PO₄)₃ Coating
2020
In this work, a fast ionic conductor, Li₁.₃Al₀.₃Ti₁.₇(PO₄)₃ (LATP), has been successfully coated on a Ni-rich LiNi₀.₈Co₀.₁Mn₀.₁O₂ surface by an improved sol–gel method with postannealing at 575 °C. A series of electrochemical tests along with X-ray diffraction, scanning electron microscopy (SEM), energy dispersive spectrometry, transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) are executed to study the physical characteristics and electrochemical properties of pristine LiNi₀.₈Co₀.₁Mn₀.₁O₂ and LATP-coated LiNi₀.₈Co₀.₁Mn₀.₁O₂ samples. Electrochemical results show that 0.5 wt % LATP-coated LiNi₀.₈Co₀.₁Mn₀.₁O₂ exhibits the best electrochemical performance. In particular, 0.5 wt % LATP coating delivers great cycling stability with a capacity retention rate of 84.5% after 200 cycles at 2 C, while the pristine sample has a capacity retention rate of only 67.39%. The SEM-backscattered electron and TEM results of materials after cycling show that LATP coating can effectively improve the structural stability of the LiNi₀.₈Co₀.₁Mn₀.₁O₂ cathode.
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