Controlling Molecular Ordering in Aqueous Conducting Polymers Using Ionic Liquids
2016
: The molecular ordering of aqueous conducting polymers is controlled using a rational method. By introducing various ionic liquids, which have designed electrostatic interactions to PEDOT:PSS solutions, the evolution of the molecular ordering of the PEDOT is manipulated. Consequently, highly ordered nanostructures are achieved with a reduced π-π stacking distance of ≈3.38 A and, thus, a maximum σdc of ≈2100 S cm-1 .
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