Polycrystalline texture causes magnetic instability in greigite.

2021 
Magnetic stability of iron mineral phases is a key for their use as paleomagnetic information carrier and their applications in nanotechnology, and it critically depends on the size of the particles and their texture. Ferrimagnetic greigite (Fe3S4) in nature and synthesized in the laboratory forms almost exclusively polycrystalline particles. Textural effects of inter-grown, nano-sized crystallites on the macroscopic magnetization remain unresolved because their experimental detection is challenging. Here, we use ferromagnetic resonance (FMR) spectroscopy and static magnetization measurements in concert with micromagnetic simulations to detect and explain textural effects on the magnetic stability in synthetic, polycrystalline greigite flakes. We demonstrate that these effects stem from inter-grown crystallites with mean coherence length (MCL) of about 20 nm in single-domain magnetic state, which generate modifiable coherent magnetization volume (CMV) configurations in the flakes. At room temperature, the instability of the CVM configuration is exhibited by the angular dependence of the FMR spectra in fields of less than 100 mT and its reset by stronger fields. This finding highlights the magnetic manipulation of polycrystalline greigite, which is a novel trait to detect this mineral phase in Earth systems and to assess its fidelity as paleomagnetic information carrier. Additionally, our magneto-spectroscopic approach to analyse instable CMV opens the door for a new more rigorous magnetic assessment and interpretation of polycrystalline nano-materials.
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