Effective and Rapid Removal of Polar Organic Micropollutants from Water by Amide Naphthotube-Crosslinked Polymers

It is challenging to remove polar organic micropollutants from water through adsorption-mediated processes. Macrocycle-crosslinked polymers were recently shown to be effective adsorbents for nonpolar or charged organic micropollutants through specific host-guest binding, but are rarely used for the treatment of neutral and polar organic micropollutants. This is due to the challenge of recognizing polar molecules in water by macrocyclic hosts. In this research, we report two amide naphthotube-crosslinked polymers which can effectively and rapidly adsorb a wide scope of polar organic micropollutants from water through biomimetic molecular recognition. Amide naphthotubes possess hydrogen bonding sites in their deep hydrophobic cavities and can effectively bind polar organic micropollutants in water through the hydrophobic effects and shielded hydrogen bonds. The cross-linked polymers containing amide naphthotubes are even able to remove a complex mixture of organic micropollutants from water and the used materials can be easily regenerated through washing with MeOH or EtOH. This research provides a solution for the treatment of polar organic micropollutants by using biomimetic molecular recognition in water.