Optical Microscope Absorbance Imaging of Carbon Black Nanoparticle Films at Solid and Liquid Surfaces

We have used an optical transmission microscope equipped with a digital camera and fitted with a narrow-band-pass filter to obtain absorbance images consisting of an array of pixel absorbance values. Absorbance images of films of carbon nanoparticles were used to derive spatially resolved images of the carbon film thicknesses with a resolution in the thickness dimension of a few nanometers. The technique was applied to the characterization of carbon nanoparticle films at cellulose-coated glass surfaces and at the oil−water interfaces of emulsion drops. For the emulsions, it was necessary to use oil and water phases of equal refractive index to avoid artifacts due to the drops acting as lenses.