Ammonia emission control in China would mitigate haze pollution and nitrogen deposition, but worsen acid rain

China has been experiencing fine particle (i.e., aerodynamic diameters ≤ 2.5 µm; PM 2.5 ) pollution and acid rain in recent decades, which exert adverse impacts on human health and the ecosystem. Recently, ammonia (i.e., NH 3 ) emission reduction has been proposed as a strategic option to mitigate haze pollution. However, atmospheric NH 3 is also closely bound to nitrogen deposition and acid rain, and comprehensive impacts of NH 3 emission control are still poorly understood in China. In this study, by integrating a chemical transport model with a high-resolution NH 3 emission inventory, we find that NH 3 emission abatement can mitigate PM 2.5 pollution and nitrogen deposition but would worsen acid rain in China. Quantitatively, a 50% reduction in NH 3 emissions achievable by improving agricultural management, along with a targeted emission reduction (15%) for sulfur dioxide and nitrogen oxides, can alleviate PM 2.5 pollution by 11−17% primarily by suppressing ammonium nitrate formation. Meanwhile, nitrogen deposition is estimated to decrease by 34%, with the area exceeding the critical load shrinking from 17% to 9% of China’s terrestrial land. Nevertheless, this NH 3 reduction would significantly aggravate precipitation acidification, with a decrease of as much as 1.0 unit in rainfall pH and a corresponding substantial increase in areas with heavy acid rain. An economic evaluation demonstrates that the worsened acid rain would partly offset the total economic benefit from improved air quality and less nitrogen deposition. After considering the costs of abatement options, we propose a region-specific strategy for multipollutant controls that will benefit human and ecosystem health.