New insight of sedimentological and geochemical characterization of siliciclastic-carbonate deposits (Alveolina Limestone Formation, Graus-Tremp basin, Spain)

This article is a first attempt of combining sedimentological analysis and geochemical systematics of the Alveolina Limestone Formation as a tool to identify the major stratigraphic surfaces, and to improve the sequence stratigraphy interpretation. This formation is Early Eocene in age and crops out in several well-exposed cliffs in the Serraduy – Roda de Isabena area (Graus-Tremp basin, NE Spain). Within this succession, nineteen carbonate and siliciclastic facies have been identified and grouped in environmental facies associations (based on their vertical stacking and lateral relationships): 1) coastal plain; 2) clastic deltaic complex; 3) shallow carbonate inner-ramp; 4) mid-ramp; 5) outer-ramp; 6) reefal facies. The depositional architectures studied in the Serraduy area can be directly assessed on the field, and a 3D reconstruction is proposed. This enables us to build a synthetic depositional model and to identify five small-scale T/R cycles, bounded by different kinds of sedimentary discontinuities : angular unconformity, firmground, erosional surface… In parallel, geochemical analyses (C and O isotopes, major, minor and trace elements) were carried out to help at hierarchizing the cycles and the boundaries previously identified. Four of them may be considered as major stratigraphic surfaces, corresponding either to regional-scale angular unconformities, or to exposure surfaces. The latter are characterized by a selective dissolution, a slight but sharp decrease in δ13C V-PDB and in Mg, Fe and Sr contents below the surface. The absence of typical sedimentary criteria of exposure (with the exception of these geochemical signatures) may be explained by short-term exposure, an arid to semi-arid climate, and a dominant low-magnesian calcite original mineralogy, precluding the development and the preservation of widespread vadose diagenetic products. A new sequence stratigraphy model for the Alveolina Limestone Fm is finally proposed and discussed.