Effect of Ag on aging precipitation behavior and mechanical properties of aluminum alloy 7075

Abstract Effects of Ag addition on the age hardening and precipitation behavior of aluminum alloy 7075 were investigated. The transmission electron microscopy (TEM) and atom probe tomography (APT) were used to study the aggregate distribution and identify the role of Ag in precipitation hardening of the alloy. The hardness and strength of the Ag–containing alloy were increased by more than 10% due to a higher number density of fine aggregates, which was 2.5 times that of the Ag–free alloy 7075. Both T–type and η–type precipitates existed in the alloys, and two precipitation sequences occurred simultaneously as: SSS → η–type cluster → GP zone → η′ → η → T, and SSS → T–type cluster → GP zone→ T′ → T. Particularly, Ag promoted the formation of T–type clusters due to the interaction among Ag, Mg and Zn atoms as well as vacancies at the early stage of aging. The Mg–Ag, Zn–Ag, and vacancy–Ag co–clusters acted as nucleation sites for the subsequent precipitates (η′, T′, etc.). This also caused the increase of Mg concentration in T–type clusters at the beginning of aging and the narrowing of the precipitation free zone (PFZ) near grain boundaries at the peak aging.