Macrocyclic Diacetylene-Terthiophene Cocrystal: Molecular Self-Assembly, Topochemical Polymerization and Energy Transfer

The macrocyclic structure offers direction-control self-assembly to generate columnar supramolecular architectures with a guest molecule-accessible interior cavity. Owing to the π–π stacking characteristic and photopolymerizable feature of the diacetylenic template, macrocyclic diacetylenes (MCDAs) have emerged as an intriguing molecular design for constructing arrays of covalently connected nanochannels. The energy transfer mechanism by engineering host–guest cocrystals of self-assembling π-electron-rich motifs has been widely accepted for devising organic electronics. A highly fluorescent and polymerizable cocrystal of macrocyclic diacetylene-terthiophene (MCDA-3T) was constructed. Single-crystal X-ray diffraction analysis reveals well-ordered columnar assembly of MCDA with stacking geometry close-to-ideal packing parameters preferred for the topochemical polymerization. Inspection of the extended crystal packing pattern and by elemental analysis confirms the inclusion of the 3T guest in outer-space pos...