The fifty years it has taken to understand the dynamics of UO 2 in its ordered state

: In 1966 Roger Cowley (together with Gerald Dolling) reported the first neutron inelastic scattering from the magnetic excitations from UOlsubg2l/subg below its antiferro-magnetic ordering temperature of 31 K. They showed the strong magnon-phonon coupling in this material and that the excitations appeared to contain an additional mode that was not anticipated. Cowley never returned to UOlsubg2l/subg, but showed a keen interest in the developments. 40 years after this pioneering work, unambiguous evidence was found (using resonance X-ray techniques) for the ordering below TlsubgNl/subg of the electric quadrupoles involving the anisotropy of the 5ligf l/igcharge distribution around the uranium nuclei. A further 10 years later, now armed with a full theory for the excitation spectrum expected for phonons, magnons, and quadrupoles, we can identify the latter as the source of the "extra" mode reported first in 1966. The story is a long winding one, with the expected serendipity and dead ends, but is now (almost) completed. .