Photolytic generation of an o-quinodimethane derivative and its reactions with unsaturated polymers
1998
Polybutadiene was treated with o-tolualdehyde under UV irradiation to produce random copolymers through Diels-Alder reactions on the backbone double bonds. The physical properties of the polymer products change as more of the aldehyde attaches to it. The copolymers were characterized by NMR spectroscopy. A bifunctional o-tolualdehyde was synthesized and used as a crosslinking agent.
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