Synthesis of fused conjugated polymers containing imidazo[2,1-b]thiazole units by multicomponent one-pot polymerization
2020
We herein report a facile and efficient multicomponent polymerization approach to construct fused heterocyclic polymers with imidazo[2,1-b]thiazole units in the main chain. A preliminary polymerization reaction was carried out as a model reaction with 1,4-phthalaldehyde, [6,6'-bibenzothiazole]-2,2'-diamine and 1-ethynyl-4-hexylbenzene as monomers, the different polymerization conditions, including catalyst, catalyst amount and solvent, were optimized. Based on the optimized conditions, a series of fused heterocyclic conjugated polymers containing imidazo[2,1-b]thiazole units with high-molecular weight (Mn up to 5.7 x 104) in moderate yields (up to 54.3%) were obtained. With imidazo[2,1-b]thiazoles embedded in the main chains, the resulting polymers possess outstanding good solubility, relatively good thermal stability and low energy band. A possible mechanism was proposed for the polymerization including a 5-exo-dig cyclization and then aromatization process.
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