Exploring Structural Disorders in Aluminum-Containing Metal–Organic Frameworks: Comparison of Solid-State 27Al NMR Powder Spectra to DFT Calculations on Bulk Periodic Structures

We use solid-state 27Al NMR spectroscopy to test four aluminum-based metal–organic framework (MOF) materials—ICR-2, ICR-4, ICR-6, and ICR-7—against their structural models obtained from electron an...