Synergistic Ni single atoms and oxygen vacancies on SnO2 nanorods toward promoting SO2 gas sensing

Abstract Monitoring sulfur dioxide (SO2) in the environment requires a sensor to feature adequate sensitivity, selectivity, and low detection levels. Herein, we report an ultrasensitive, low-concentration SO2 gas sensor that employs single atoms nickel anchored on oxygen vacancy-rich SnO2 nanorods (SAC-Ni/H-SnO2) as the sensing material. The response value of the SAC-Ni/H-SnO2 sensor to 20 ppm SO2 is 48, and the detection limit is 100 ppb, which is superior to most of reported SO2 sensors. In-situ DRIFTS and ESR characterization shows that the coupling effects of SAC-Ni and adjacent oxygen vacancy on SnO2 surface, which promote the adsorption of SO2 and activation of chemisorbed oxygen, respectively. This effective single-atom catalyst provides a new insight into complex gas sensing mechanisms and demonstrates a promising approach of using single-atom catalysts for gas sensing applications.