Synthesis and electrochemical performance of hierarchical nanocomposite of carbon coated LiCoPO4 crosslinked by graphene
2016
Abstract We report the design and synthesis of a novel hierarchical LiCoPO 4 @C/G cathode material, consisting of carbon coated LiCoPO 4 nanoparticles crosslinked by wrinkled graphene, for high-energy-density lithium ion batteries. This material is facilely prepared by a solid-state milling process followed by heat annealing. Its morphology and structure are characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy and X-ray diffraction. It is revealed that the LiCoPO 4 nanoparticles are coated by an amorphous carbon layer with ∼3 nm thickness and further crosslinked by wrinkled graphene. The LiCoPO 4 @C/G material delivers a high discharge capacity of 146.1 mAh g −1 at 0.1 C rate and 93.0 mAh g −1 at 2 C rate. The enhanced electrochemical properties are attributed to the nanosized LiCoPO 4 particles and the high electronic conductivity resulted from the synergistic carbon coating and graphene crosslinking. Our work provides a facile approach to prepare high performance LiCoPO 4 cathode materials for lithium ion batteries.
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