Encapsulation of CoSx Nanocrystals into N/S Co‐Doped Honeycomb‐Like 3D Porous Carbon for High‐Performance Lithium Storage
2018
: A honeycomb-like 3D N/S co-doped porous carbon-coated cobalt sulfide (CoS, Co9S8, and Co1-x S) composite (CS@PC) is successfully prepared using polyacrylonitrile (PAN) as the nitrogen-containing carbon source through a facile solvothermal method and subsequent in situ conversion. As an anode for lithium-ion batteries (LIBs), the CS@PC composite exhibits excellent electrochemical performance, including high reversible capacity, good rate capability, and cyclic stability. The composite electrode delivers specific capacities of 781.2 and 466.0 mAh g-1 at 0.1 and 5 A g-1, respectively. When cycled at a current density of 1 A g-1, it displays a high reversible capacity of 717.0 mAh g-1 after 500 cycles. The ability to provide this level of performance is attributed to the unique 3D multi-level porous architecture with large electrode-electrolyte contact area, bicontinuous electron/ion transport pathways, and attractive structure stability. Such micro-/nanoscale design and engineering strategies may also be used to explore other nanocomposites to boost their energy storage performance.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
64
References
104
Citations
NaN
KQI