Laser Lithography of a Tube-in-a-Tube Nanostructure

Carbon nanotubes hold vast potential for device innovations because their optical and electronic properties can be synthetically tailored at a length scale unattainable by lithographic techniques. However, lithographic patterning of carbon nanotubes with electronic-type control remains one of the major problems for the integration of these nanomaterials for practical device applications. In this work, we propose a laser lithography method for direct-write patterning of devices on thin films of outer wall selectively functionalized double-walled carbon nanotubes (Tube^2). This method is enabled by the reversible removal of surface functional groups with a laser tuned into resonance with the inner tube of Tube^2. We show that it is possible to directly create patterned dot arrays and conductive pathways and circuits on insulating Tube^2 thin films by tuning the resonance of the direct-writing laser with the electronic type of the inner tube (i.e., metallic or semiconducting). The successful patterning was u...