Phosphonic Acid Modification of the Electron Selective Contact: Interfacial Effects in Perovskite Solar Cells
2019
The role electron-transport layers (ETLs) play in perovskite solar cells (PSCs) is still widely debated. Conduction band alignment at the perovskite/ETL interface has been suggested to be important role for the performance of the solar cells. However, little is known about the effects of work-function shifts on the solar-cell performance, and specifically, the open-circuit voltage (VOC). Here the effects of surface modification of SnO2 ETLs using polar phosphonic acids are investigated, including the effects on work-function, surface energy, device performance, and device stability in inert atmosphere. The phosphonic acid modifications did not have a large effect on VOC; however, a sharp decrease in overall device performance was found, mostly due to reduced fill factors. When exposed to conditions of low oxygen concentration, the phosphonic acid-surface-modified devices yielded current-voltage (J-V) curves with considerably lower hysteresis than those based on unmodified SnO2. This suggests that this mod...
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