Highly Active PdCu/Graphene Catalyst for Efficient Suzuki Cross-coupling Reaction

A graphene supported Pd–Cu bimetallic catalyst (Pd–Cu/G) has been successfully fabricated by a simple one-pot solvothermal reaction. X-ray diffraction (XRD) analysis as well as morphology characterization demonstrated that Pd–Cu nanoparticles (NPs) are uniformly distributed on the graphene nanosheets. When adopted as the catalyst for the Suzuki cross-coupling reaction, this hybrid exhibited excellent catalytic activity (99.9% conversion) as well as desirable selectivity (99.9%). After recycling five times, the high yield and selectivity were well maintained, illustrating the high durability of this catalyst.