The effect of dislocations on the transport properties of III/V‐compound semiconductors on Si

The transport properties of InP and GaAs epitaxial layers grown on exactly (001)‐oriented Si substrates were investigated by temperature‐dependent van der Pauw measurements combined with anodic stripping. Electron concentrations n at T=300 K decreasing from around 1018 cm−3 at the heterointerface to a constant level of 1016 cm−3 toward the surface agree well with the concentration profile of Si donors. Their activation energy is 2.9 and 1.3 meV in InP/Si and GaAs/Si, respectively. At low temperatures a marked decrease of the electron mobility μ at the heterointerface occurred. A quantitative analysis of μ (T) led to the model of charged dislocations as scattering centers. By comparison with the dislocation densities of 2×108 and 1×108 cm−2 in the vicinity of the surface of 2‐ and 3‐μm‐thick layers found by wet chemical etching we derived the occupation probability of the charged centers along the dislocation lines as 0.2 and 1.0 for InP and GaAs, respectively. At 300 K μ was almost unaffected by dislocati...