Catalytic, Enantio‐ and Diastereoselective Synthesis of γ‐Butyrolactones Incorporating Quaternary Stereocenters.

Francesco Manoni,Claudio Cornaggia,James Murray,Sean Tallon,Stephen J. Connon

Catalytic, Enantio‐ and Diastereoselective Synthesis of γ‐Butyrolactones Incorporating Quaternary Stereocenters.

2012

Francesco Manoni
Claudio Cornaggia
James Murray
Sean Tallon
Stephen J. Connon

The formal cycloaddition of aryl succinic anhydrides (I) with aldehydes (II) and (V) gives rise to aryl paraconic acids with 76-98% diastereoselectivity.

Keywords:

Succinic anhydride
Stereocenter
Aryl
Cycloaddition
Catalysis
Chemistry
Organic chemistry

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