Microstructure evolution of Li uptake/removal in MoO2@C nanoparticles with high lithium storage performance
2014
Abstract A facile one pot strategy of a hydrothermal methodology was applied to synthesize the carbon coated MoO 2 (MoO 2 @C) nanostructured particles, which are composed of ultra fine nanoparticles with homogeneous carbon coating about several nanometers. As an electrode in lithium ion batteries, the MoO 2 @C shows a high specific capacity and reversible capacity (730 mA h g −1 after 60 cycles). Microstructure investigations, by using a high resolution transmission electron microscopy, of the MoO 2 @C based electrodes employed at various states during the first discharge/charge cycle were conducted to elucidate the lithium ion uptake/removal mechanism and cycling behavior. In the lithium uptake process, the original MoO 2 phase transfers into Li 0.98 MoO 2 through an addition type reaction, and then nanosized metallic Mo emerges as a result of a conversion reaction. In turn, Mo could be oxidized to the intermediate Li 0.98 MoO 2 before converting to hyperfine MoO 2 phase on upcoming lithium removal process.
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