Estimation of spectroscopic parameters and colour purity of the red-light-emitting YBa3B9O18 phosphor: Judd–Ofelt approach

Abstract Herein, Eu 3+ doped YBa 3 B 9 O 18 (YBB) phosphors have been synthesized via the solid state reaction method. The formation of YBB structure is confirmed via X-ray diffraction (XRD) studies and Rietveld refinement. The photoluminescence (PL) emission measurements upon excitation by ultraviolet and visible light show the characteristics emission of Eu 3+ ion due to the 5 D 0 → 7 F J transitions. The occurrence of charge transfer band in the excitation spectra has been explained in details. The PL intensity is seen to be increased with the increase of Eu 3+ concentration up to 2 mol% and then decreased because of the concentration quenching. The critical distance for the quenching mechanism is calculated to be 11.83 A suggesting dipole-dipole interactions between Eu 3+ ions. Different spectroscopic parameters are calculated from the emission spectra of Eu 3+ ion via Judd–Ofelt theory. The results indicate the strong covalent and asymmetric nature of Eu 3+ in YBB host. The as estimated values of transition probabilities indicate the efficiency of 5 D 0 → 7 F 2 transition and support the enhancement of the red colour emission. The red colour purity is increased with the increase in Eu 3+ concentration and obtained to be 91% for the 2 mol% Eu 3+ doped sample. This has been explained on the basis of electron phonon coupling and multipolar interaction. The purity of the red emission has been checked and the obtained results indicate the suitability of Eu 3+ doped YBB as a promising candidate for the lighting and display applications.