Atomic Ir-doped NiCo layered double hydroxide as bifunctional electrocatalyst for highly efficient and durable water splitting

Developing cost-effective bifunctional electrocatalysts with low kinetic overpotential and superior stability for both the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is crucial to build water splitting system for advancing the production of hydrogen fuel. Herein, we report a bifunctional catalyst by doping atomic Ir into the NiCo layered double hydroxide (LDH) using a facile atmospheric solvothermal method and subsequently spontaneous galvanic displacement. The as-synthesized atomic Ir-doped NiCo LDH exhibits much better durability for over 200 h than the NiCo LDH with the loading of Ir nanoparticles, due to the fine doping of atomic Ir into the crystal lattice of LDH. Benefiting from the synergistic effects in HER/OER processes, as well as the large electrochemical active surface area and the improved electrical conductivity, the atomic Ir-doped NiCo LDH couple results in the unprecedented performance for overall water splitting with a low cell voltage of 1.45 V at 10 mA/cm2 in 1.0 M KOH electrolyte. Finally, a practical solar-driven water splitting system with a solar-to-hydrogen efficiency of 14.8% was demonstrated, outperforming the state-of-the-art analogous systems based on the ordinary Si solar cells.