Dendrite-free lithium anode achieved under lean-electrolyte condition through the modification of separators with F-functionalized Ti3C2 nanosheets

Abstract An unstable solid electrolyte interphase (SEI) and chaotic lithium ion flux are key impediments to commercial high-energy-density lithium batteries because of the uncontrolled growth of rigid lithium dendrites, which would pierce through the conventional polypropylene (PP) separator, causing short circuit and safety issues. Herein, the homogenization of lithium ion flux and the generation of stable SEI layers on lithium anodes were achieved via coating a fluorine-functionalized Ti3C2 (F-Ti3C2) nanosheets on PP separator (F-Ti3C2@PP). F-Ti3C2 nanosheets provide abundant ions pathways to homogeneously manipulate lithium ion flux and increase the Young’s modulus and electrolyte wettability of the separators. In addition, F species derived from the F-Ti3C2 nanosheets would promote the formation of LiF-rich SEI film. The synergistic effect contribute to the uniform lithium deposition. Symmetric Li|Li, asymmetric Li|Cu and full Li|LiFePO4 cells incorporated with the modified separators exhibit improved electrochemical performance even under lean electrolyte conditions. This work provides a feasible strategy to improve the performance of lithium batteries through both fluoridized SEI formation and lithium ion flux manipulation.