Structural changes of cerium doped copper ferrites during sintering process and magneto-electrical properties assessment

Abstract Crystalline CuCe x Fe 2-x O 4 nanoparticles with different rare earth metal content (x = 0.00, 0.03, 0.05, 0.08 and 0.10) were synthesized using a co-precipitation technique that involves a 600 °C calcination treatment. The newly obtained powders were pressed into pellets and heated up to 950 °C in order to form a compact and less porous material, ideal for dielectric measurements. X-ray investigations revealed a structural modification from typical cubic system to a tetrahedral spinel form, accompanied by Ce 3+ cations exclusion and formation of secondary phases. The amount of phases and cations distribution were determined by Rietveld refinement method. A degradation process of cerium doped copper ferrite was proposed based on X-ray analysis and Rietveld refinement. Furthermore, the magnetic behavior of both 600 °C and 950 °C samples was investigated from the hysteresis loops recorded from a vibrating sample magnetometer (VSM) in a ±10 kOe range. Room temperature dielectric values for the 950 °C samples were determined using the parallel-plate capacitor configuration in a frequency range of 10 Hz – 1 MHz.