Single-Chain and Monolayered Conjugated Polymers for Molecular Electronics

Abstract Exploring the charge transport properties and electronic functions of molecules is of primary interest in the area of molecular electronics. Conjugated polymers (CPs) represent an attractive class of molecular candidates, benefiting from their outstanding optoelectronic properties. However, they have been less studied compared with the small-molecule family, mainly due to the difficulties in incorporating CPs into molecular junctions. In this review, we present a summary on how to fabricate CP-based single-chain and monolayered junctions, then discuss the transport behaviors of CPs in different junction architectures and finally introduce the potential applications of CPs in molecular-scale electronic devices. Although the research on CP-based molecular electronics is still at the initial stage, it is widely accepted that (1) CP chains are able to mediate long-range charge transport if their molecular electronic structures are properly designed, which makes them potential molecular wires, and (2) the intrinsic optoelectronic properties of CPs and the possibility of incorporating desirable functionalities by synthetic strategies imply the potential of employing tailor-made polymeric components as alternatives to small molecules for future molecular-scale electronics.