Toughening of Cocontinuous Polylactide/Polyethylene Blends via an Interfacially Percolated Intermediate Phase
2018
It will be shown that an interfacially percolated rubbery phase in a cocontinuous polylactide (PLA)/linear low-density polyethylene (LLDPE) blend results in a significant increase in the impact strength. All blends possess a tricontinuous phase morphology in which poly(e-caprolactone) (PCL), poly(ethylene–methyl acrylate) (EMA), and ethylene–methyl acrylate–glycidyl methacrylate (EMA-GMA) percolate at the interface of PLA/LLDPE but offer different toughening and compatibilization effects. Among these components, the addition of EMA-GMA to the binary PLA/LLDPE blend reduces the cocontinuous PLA/LLDPE phase thickness from about 25 to 5 μm and yields a very tough material with an impact strength of about 515 J/m, which is approximately 13 times greater than the original cocontinuous PLA/LLDPE blend and more than 32 times that of PLA. The ternary blends show significant improvements in the impact strength within the tricontinuous region; however, the principal differences in the toughening effects are attribu...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
48
References
44
Citations
NaN
KQI